(Acetylacetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
نویسندگان
چکیده
In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl-acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand. The dicyanamide N atoms are each involved in hydrogen bonds to water mol-ecules. There are also hydrogen bonds between both the water mol-ecules and their centrosymmetric pairs, creating a hydrogen-bonded chain along the b-axis direction.
منابع مشابه
Bis(1,10-phenanthroline-κ2 N,N′)[2-(4-sulfonatoanilino)acetato-κO]copper(II) dihydrate
In the title compound, [Cu(C(8)H(7)NO(5)S)(C(12)H(8)N(2))(2)]·2H(2)O, the Cu(II) ion is coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and one O atom from a 2-(4-sulfonato-anilino)acetate (spia) ligand in a distorted square-pyramidal geometry. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds, as well as π-π inter-actions between phen ligands and between phen and spia liga...
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